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Informal Progress Report: Acid-Base Behavior in Hydrothermal Processing of Wastes DE-FG07-96ER14687 A major obstacle to the development of hydrothermal technology for treating DOE wastes has been a lack of scientific knowledge of solution chemistry, thermodynamics and transport phenomena.. Ion Solvation in Supercritical Water Based on an Adsorption Analogy The solvation structure and free energy for Li + , Na + , K + , F , C1-, Be2+, Mg +, and Ca2+ in supercritical aqueous solutions are described by a dielectric concentric shell model incorporating solvent adsorption analogous to a Langmuir model..